When you first start homeschooling, it can be a daunting task. One of the best things you can do right away is get connected with a support group. If you don't have a local group to join, you may have to create a group yourself.
WikiHow has a really good overview (Create a Homeschool Network from Scratch) to get you started.
As you learn more, or have ideas, please feel free to add to this page.